“The steam-engine having furnished us with a means of converting heat into a motive power, and our thoughts being thereby led to regard a certain quantity of work as an equivalent for the amount of heat expended in its production, the idea of establishing theoretically some fixed relation between a quantity of heat and the quantity of work which it can possibly produce, from which relation conclusions regarding the nature of heat itself might be deduced, naturally presents itself. Already, indeed, have many successful efforts been made with this view; I believe, however, that they have not exhausted the subject, but that, on the contrary, it merits the continued attention of physicists… The most important investigation in connexion with this subject is that of S. Carnot.”

— Rudolf Clausius

First Memoir. On the Moving Force of Heat and the Laws which may be Deduced Therefrom
The Mechanical Theory of Heat (1867)

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Rudolf Clausius 6

German mathematical physicist 1822–1888

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“The careful experiments of Joule, who developed heat in various ways by the application of mechanical force, establish almost to a certainty, not only the possibility of increasing the quantity of heat, but also the fact that the newly-produced heat is proportional to the work expended in its production.”

Rudolf Clausius (1822–1888) German mathematical physicist

First Memoir.
The Mechanical Theory of Heat (1867)

“Many facts have lately transpired which tend to overthrow the hypothesis that heat is itself a body, and to prove that it consists in a motion of the ultimate particles of bodies. If this be so, the general principles of mechanics may be applied to heat; this motion may be converted into work, the loss of vis viva in each particular case being proportional to the quantity of work produced.
These circumstances, of which Carnot was also well aware, and the importance of which he expressly admitted, pressingly demand a comparison between heat and work, to be undertaken with reference to the divergent assumption that the production of work is not only due to an alteration in the distribution of heat, but to an actual consumption thereof; and inversely, that by the expenditure of work, heat may be produced.”

Rudolf Clausius (1822–1888) German mathematical physicist

First Memoir.
The Mechanical Theory of Heat (1867)

“Nature, in providing us with combustibles on all sides, has given us the power to produce, at all times and in all places, heat and the impelling power which is the result of it. To develop this power, to appropriate it to our uses, is the object of heat-engines.”

Nicolas Léonard Sadi Carnot (1796–1832) French physicist, the "father of thermodynamics" (1796–1832)

p, 125
Reflections on the Motive Power of Heat (1824)

“The phenomenon of the production of motion by heat has not been considered from a sufficiently general point of view. We have considered it only in machines… [for which] the phenomenon is… incomplete. It becomes difficult to recognize its principles and study its laws. …[T]he principle of the production of motion by heat… must be considered independently of any mechanism or… particular agent. It is necessary to establish principles applicable not only to steam-engines but to all imaginable heat-engines, whatever the working substance and whatever the method by which it is operated.”

Nicolas Léonard Sadi Carnot (1796–1832) French physicist, the "father of thermodynamics" (1796–1832)

Reflections on the Motive Power of Heat (1824)

“This law (regarding the theoretical efficiency of heat engines by Mr. Joule), and the law of the maximum efficiency of heat engines, are particular cases of a general law which regulates all transformation of energy, and is the basis of the Science of Energetics.”

William John Macquorn Rankine (1820–1872) civil engineer

Manual of Applied Mechanics, (1858) London and Glasgow : Richard Griffin and Company, p. 630

“I have endeavoured to attain this end (viz. the production of a vacuum in the cylinder) in another way. As water has the property of elasticity, when converted into steam by heat, and afterwards of being so completely recondensed by cold, that there does not remain the least appearance of this elasticity, I have thought that it would not be difficult to work machines in which, by means of a moderate heat and at a small cost, water might produce that perfect vacuum which has vainly been sought by means of gunpowder.”

Denis Papin (1647–1713) French physicist, mathematician and inventor

Denis Papin, Recueil de diverses Pièces touchant quelques nouvelles Machines (1695) p. 53 as quoted by Dionysius Lardner, The Steam Engine Explained and Illustrated (1840) pp. 45-46

“I see the expression of… economy clearly in the gradual reduction of the statical laws of machines to a single one, viz., the principle of virtual work: in the replacement of Kepler's laws by Newton's single law… and in the [subsequent] reduction, simplification and clarification of the laws of dynamics. I see clearly the biological-economical adaptation of ideas, which takes place by the principles of continuity (permanence) and of adequate definition and splits the concept 'heat' into the two concepts of 'temperature' and 'quantity of heat'; and I see how the concept 'quantity of heat' leads on to 'latent heat', and to the concepts of 'energy' and 'entropy.”

Ernst Mach (1838–1916) Austrian physicist and university educator

Mach (1910) "Die Leitgedanken meiner naturwissenschaftlichcn Erkennenislehre und ihr Aufnahme durch die Zeitgenossen", Physikalische Zeitschrift. 1, 1910, 599-606 Eng. trans. as "The Guiding Principles of my Scientific Theory of Knowledge and its Reception by my Contemporaries", in S. Toulmin ed., Physical Reality, New York : Harper, 1970. pp.28-43. Cited in: K. Mulligan & B. Smith (1988) " Mach and Ehrenfels: Foundations of Gestalt Theory http://ontology.buffalo.edu/smith/articles/mach/mach.pdf"
20th century

“The switch from 'steam engines' to 'heat engines' signals the transition from engineering practice to theoretical science.”

Hans Christian von Baeyer (1938) American physicist

Source: Information, The New Language of Science (2003), Chapter 18, Information is Physical, The cost of forgetting, p. 154

“This consideration must alter the form of our proposed inquiry; for the question being thus at least partly decided, since it is ascertained that we have rays of heat which give no light, it can only become a subject of inquiry whether some of these heat-making rays may not have a power of rendering objects visible, superadded to their now already established power of heating bodies.”

William Herschel (1738–1822) German-born British astronomer, technical expert, and composer

This being the case, it is evident that the onus probandi [burden of proof] ought to lie with those who are willing to establish such an hypothesis, for it does not appear that Nature is in the habit of using one and the same mechanism with any two of our senses. Witness the vibration of air that makes sound, the effluvia that occasion smells, the particles that produce taste, the resistance or repulsive powers that affect the touch—all these are evidently suited to their respective organs of sense.
Source: Sir William Herschel: His Life and Works (1880), Ch.4 "Life and Works" on his discovery of the infrared.

“By another way, therefore, I endeavoured to attain the same end; and since it is a property of water that a small quantity of it, converted into steam by the force of heat, has an elastic force like that of the air, but, when cold supervenes, is again resolved into water, so that no trace of the said elastic force remains; I felt confident that machines might be constructed wherein water, by means of no very intense heat, and at small cost, might produce that perfect vacuum which had failed to be obtained by aid of gunpowder. But of the various constructions which can be contrived for this purpose, the following seemed to me to be the most suitable.”

Denis Papin (1647–1713) French physicist, mathematician and inventor

"A New Method of Obtaining Very Great Moving Powers at Small Cost" (1690)

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Rudolf Clausius 6

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