“In thermodynamics as well as in other branches of molecular physics, the laws of phenomena have to a certain extent been anticipated, and their investigation facilitated, by the aid of hypotheses as to occult molecular structures and motions with which such phenomena are assumed to be connected.”

Source: A Manual of the Steam Engine and Other Prime Movers (1859), p. 31
Context: Hypothesis Of Molecular Vortices. In thermodynamics as well as in other branches of molecular physics, the laws of phenomena have to a certain extent been anticipated, and their investigation facilitated, by the aid of hypotheses as to occult molecular structures and motions with which such phenomena are assumed to be connected. The hypothesis which has answered that purpose in the case of thermodynamics, is called that of "molecular vortices," or otherwise, the "centrifugal theory of elasticity. (On this subject, see the Edinburgh Philosophical Journal, 1849; Edinburgh Transactions, vol. xx.; and Philosophical Magazine, passim, especially for December, 1851, and November and December, 1855.)

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William John Macquorn Rankine 28
civil engineer 1820–1872

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“Granted the existence of a certain kind of molecular motion, what is it that determines its direction along one path rather than another?”

William Crookes (1832–1919) British chemist and physicist

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Context: The production of motion, molar or molecular, is governed by physical laws, which it is the business of the philosopher to find out and correlate. The law of the conservation of energy overrides all laws, and it is a preeminent canon of scientific belief that for every act done a corresponding expenditure of energy must be transformed.
No work can be effected without using up a corresponding value in energy of another kind. But to us the other side of the problem is even of more importance. Granted the existence of a certain kind of molecular motion, what is it that determines its direction along one path rather than another?

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