“It is possible to express the laws of thermodynamics in the form of independent principles, deduced by induction from the facts of observation and experiment, without reference to any hypothesis as to the occult molecular operations with which the sensible phenomena may be conceived to be connected; and that course will be followed in the body of the present treatise. But, in giving a brief historical sketch of the progress of thermodynamics, the progress of the hypothesis of thermic molecular motions cannot be wholly separated from that of the purely inductive theory.”

—  William John Macquorn Rankine

Source: A Manual of the Steam Engine and Other Prime Movers (1859), p. 27

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William John Macquorn Rankine 28
civil engineer 1820–1872

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“In thermodynamics as well as in other branches of molecular physics, the laws of phenomena have to a certain extent been anticipated, and their investigation facilitated, by the aid of hypotheses as to occult molecular structures and motions with which such phenomena are assumed to be connected.”

William John Macquorn Rankine (1820–1872) civil engineer

Source: A Manual of the Steam Engine and Other Prime Movers (1859), p. 31
Context: Hypothesis Of Molecular Vortices. In thermodynamics as well as in other branches of molecular physics, the laws of phenomena have to a certain extent been anticipated, and their investigation facilitated, by the aid of hypotheses as to occult molecular structures and motions with which such phenomena are assumed to be connected. The hypothesis which has answered that purpose in the case of thermodynamics, is called that of "molecular vortices," or otherwise, the "centrifugal theory of elasticity. (On this subject, see the Edinburgh Philosophical Journal, 1849; Edinburgh Transactions, vol. xx.; and Philosophical Magazine, passim, especially for December, 1851, and November and December, 1855.)

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“Science Of Energetics. Although the mechanical hypothesis just mentioned may be useful and interesting as a means of anticipating laws, and connecting the science of thermodynamics with that of ordinary mechanics, still it is to be remembered that the science of thermodynamics is by no means dependent for its certainty on that or any other hypothesis, having been now reduced, to a system of principles, or general facts, expressing strictly the results of experiment as to the relations between heat and motive power. In this point of view the laws of thermodynamics may be regarded as particular cases of more general laws, applicable to all such states of matter as constitute Energy, or the capacity to perform work, which more general laws form the basis of the science of energetics, — a science comprehending, as special branches, the theories of motion, heat, light, electricity, and all other physical phenomena.”

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Source: A Manual of the Steam Engine and Other Prime Movers (1859), p. 31

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“(Coining phrase "null hypothesis") In relation to any experiment we may speak of this hypothesis as the “null hypothesis,” and it should be noted that the null hypothesis is never proved or established, but is possibly disproved, in the course of experimentation. Every experiment may be said to exist only in order to give the facts a chance of disproving the null hypothesis.”

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“The functional validity of a working hypothesis is not a priori certain, because often it is initially based on intuition. However, logical deductions from such a hypothesis provide expectations (so called prognoses) as to the circumstances under which certain phenomena will appear in nature. Such a postulate or working hypothesis can then be substantiated by additional observations or by experiments especially arranged to test details. The value of the hypothesis is strengthened if the observed facts fit the expectation within the limits of permissible error.”

Reinout Willem van Bemmelen (1904–1983) Dutch geologist

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“The hypothesis of molecular vortices is defined to be that which assumes — that each atom of matter consists of a nucleus or central point enveloped by an elastic atmosphere, which is retained in its position by attractive forces, and that the elasticity due to heat arises from the centrifugal force of those atmospheres revolving or oscillating about their nuclei or central points.
According to this hypothesis, quantity of heat is the vis viva of the molecular revolutions or oscillations.”

William John Macquorn Rankine (1820–1872) civil engineer

"On the Centrifugal Theory of Elasticity as applied to Gases and Vapours" in The London, Edinburgh and Dublin Philosophical Magazine and Journal of Science (July-December 1851), p. 510

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“My memoirs "On the Mechanical Theory of Heat" are of different kinds. Some are devoted to the development of the general theory and to the application thereof to those properties of bodies which are usually treated of in the doctrine of heat. Others have reference to the application of the mechanical theory of heat to electricity. …Other memoirs… have reference to the conceptions I have formed of the molecular motions which we call heat. These conceptions, however, have no necessary connexion with the general theory, the latter being based solely on certain principles which may be accepted without adopting any particular view as to the nature of molecular motions. I have therefore kept the consideration of molecular motions quite distinct from the exposition of the general theory.”

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“An essential distinction exists between two stages in the process of advancing our knowledge of the laws of physical phenomena; the first stage consists in observing the relations of phenomena, whether of such as occur in the ordinary course of nature, or of such as are artificially produced in experimental investigations, and in expressing the relations so observed by propositions called formal laws. The second stage consists in reducing the formal laws of an entire class of phenomena to the form of a science; that is to say, in discovering the most simple system of principles, from which all the formal laws of the class of phenomena can be deduced as consequences.”

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Source: "Outlines of the Science of Energetics," (1855), p. 121; Lead paragraph: Section "What Constitutes A Physical Theory"

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http://www.gravett.org/bizarrescience/archives/003967.html
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