“Many facts have lately transpired which tend to overthrow the hypothesis that heat is itself a body, and to prove that it consists in a motion of the ultimate particles of bodies. If this be so, the general principles of mechanics may be applied to heat; this motion may be converted into work, the loss of vis viva in each particular case being proportional to the quantity of work produced.
These circumstances, of which Carnot was also well aware, and the importance of which he expressly admitted, pressingly demand a comparison between heat and work, to be undertaken with reference to the divergent assumption that the production of work is not only due to an alteration in the distribution of heat, but to an actual consumption thereof; and inversely, that by the expenditure of work, heat may be produced.”

— Rudolf Clausius

First Memoir.
The Mechanical Theory of Heat (1867)

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Rudolf Clausius 6

German mathematical physicist 1822–1888

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“Other qualities of bodies are connected with simple energy of motion and energy of position. Such is heat, which we find by experiment can be turned into work. Finding it convertible with energy, we call it a form of energy. ...But as to heat, it is further established by experiment that in this case the energy of motion does really persist as such. Thus a gas consists of molecules flying about with velocity, rotating and vibrating, and so having energy motion. All this energy of motion is what we call heat, and thus heat is a repetition of a known meaning of energy. Again, heat exists between a radiating body and the thing it warms; now the intermediate space is filled by the luminiferous ether, which, being elastic, has in its ultimate parts both energy of motion energy of position. In these forms the heat exists in the space in question.”

William Kingdon Clifford (1845–1879) English mathematician and philosopher

"Energy and Force" (Mar 28, 1873)

“My memoirs "On the Mechanical Theory of Heat" are of different kinds. Some are devoted to the development of the general theory and to the application thereof to those properties of bodies which are usually treated of in the doctrine of heat. Others have reference to the application of the mechanical theory of heat to electricity. …Other memoirs… have reference to the conceptions I have formed of the molecular motions which we call heat. These conceptions, however, have no necessary connexion with the general theory, the latter being based solely on certain principles which may be accepted without adopting any particular view as to the nature of molecular motions. I have therefore kept the consideration of molecular motions quite distinct from the exposition of the general theory.”

Rudolf Clausius (1822–1888) German mathematical physicist

Preface (August, 1864)
The Mechanical Theory of Heat (1867)

“The phenomenon of the production of motion by heat has not been considered from a sufficiently general point of view. We have considered it only in machines… [for which] the phenomenon is… incomplete. It becomes difficult to recognize its principles and study its laws. …[T]he principle of the production of motion by heat… must be considered independently of any mechanism or… particular agent. It is necessary to establish principles applicable not only to steam-engines but to all imaginable heat-engines, whatever the working substance and whatever the method by which it is operated.”

Nicolas Léonard Sadi Carnot (1796–1832) French physicist, the "father of thermodynamics" (1796–1832)

Reflections on the Motive Power of Heat (1824)

“The steam-engine having furnished us with a means of converting heat into a motive power, and our thoughts being thereby led to regard a certain quantity of work as an equivalent for the amount of heat expended in its production, the idea of establishing theoretically some fixed relation between a quantity of heat and the quantity of work which it can possibly produce, from which relation conclusions regarding the nature of heat itself might be deduced, naturally presents itself. Already, indeed, have many successful efforts been made with this view; I believe, however, that they have not exhausted the subject, but that, on the contrary, it merits the continued attention of physicists… The most important investigation in connexion with this subject is that of S. Carnot.”

Rudolf Clausius (1822–1888) German mathematical physicist

First Memoir. On the Moving Force of Heat and the Laws which may be Deduced Therefrom
The Mechanical Theory of Heat (1867)

“Heat can evidently be a cause of motion only by virtue of the changes of volume or of form which it produces in bodies.”

Nicolas Léonard Sadi Carnot (1796–1832) French physicist, the "father of thermodynamics" (1796–1832)

p, 125
Reflections on the Motive Power of Heat (1824)

“The hypothesis of molecular vortices is defined to be that which assumes — that each atom of matter consists of a nucleus or central point enveloped by an elastic atmosphere, which is retained in its position by attractive forces, and that the elasticity due to heat arises from the centrifugal force of those atmospheres revolving or oscillating about their nuclei or central points.
According to this hypothesis, quantity of heat is the vis viva of the molecular revolutions or oscillations.”

William John Macquorn Rankine (1820–1872) civil engineer

"On the Centrifugal Theory of Elasticity as applied to Gases and Vapours" in The London, Edinburgh and Dublin Philosophical Magazine and Journal of Science (July-December 1851), p. 510

“The careful experiments of Joule, who developed heat in various ways by the application of mechanical force, establish almost to a certainty, not only the possibility of increasing the quantity of heat, but also the fact that the newly-produced heat is proportional to the work expended in its production.”

Rudolf Clausius (1822–1888) German mathematical physicist

First Memoir.
The Mechanical Theory of Heat (1867)

“Science Of Energetics. Although the mechanical hypothesis just mentioned may be useful and interesting as a means of anticipating laws, and connecting the science of thermodynamics with that of ordinary mechanics, still it is to be remembered that the science of thermodynamics is by no means dependent for its certainty on that or any other hypothesis, having been now reduced, to a system of principles, or general facts, expressing strictly the results of experiment as to the relations between heat and motive power. In this point of view the laws of thermodynamics may be regarded as particular cases of more general laws, applicable to all such states of matter as constitute Energy, or the capacity to perform work, which more general laws form the basis of the science of energetics, — a science comprehending, as special branches, the theories of motion, heat, light, electricity, and all other physical phenomena.”

William John Macquorn Rankine (1820–1872) civil engineer

Source: A Manual of the Steam Engine and Other Prime Movers (1859), p. 31

“Rational mechanics must be the science of the motions which result from any forces, and of the forces which are required for any motions, accurately propounded and demonstrated. For many things induce me to suspect, that all natural phenomena may depend upon some forces by which the particles of bodies are either drawn towards each other, and cohere, or repel and recede from each other: and these forces being hitherto unknown, philosophers have pursued their researches in vain. And I hope that the principles expounded in this work will afford some light, either to this mode of philosophizing, or to some mode which is more true.”

Isaac Newton book Philosophiae Naturalis Principia Mathematica

Preface, translation in William Whewell's History of the Inductive Sciences http://books.google.com/books?id=vlQEAAAAQAAJ (1837)
Philosophiae Naturalis Principia Mathematica (1687)

“The whole science of heat is founded Thermometry and Calorimetry, and when these operations are understood we may proceed to the third step, which is the investigation of those relations between the thermal and the mechanical properties of substances which form the subject of Thermodynamics. The whole of this part of the subject depends on the consideration of the Intrinsic Energy of a system of bodies, as depending on the temperature and physical state, as well as the form, motion, and relative position of these bodies. Of this energy, however, only a part is available for the purpose of producing mechanical work, and though the energy itself is indestructible, the available part is liable to diminution by the action of certain natural processes, such as conduction and radiation of heat, friction, and viscosity. These processes, by which energy is rendered unavailable as a source of work, are classed together under the name of the Dissipation of Energy.”

James Clerk Maxwell (1831–1879) Scottish physicist

Theory of Heat http://books.google.com/books?id=DqAAAAAAMAAJ "Preface" (1871)

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