“To conclude, if we call light, those rays which illuminate objects, and radiant heat, those which heat bodies, it may be inquired whether light be essentially different from radiant heat? In answer to which I would suggest that we are not allowed, by the rules of philosophizing, to admit two different causes to explain certain effects, if they may be accounted for by one. …If this be a true account of the solar heat, for the support of which I appeal to my experiments, it remains only for us to admit that such of the rays of the sun as have the refrangibility of those which are contained in the prismatic spectrum, by the construction of the organs of sight, are admitted under the appearance of light and colors, and that the rest, being stopped in the coats and humors of the eye, act on them, as they are known to do on all the other parts of our body, by occasioning a sensation of heat.”

—  William Herschel

Source: Sir William Herschel: His Life and Works (1880), Ch.4 "Life and Works" on his discovery of the infrared light.

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German-born British astronomer, technical expert, and compo… 1738–1822

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William Herschel photo

“In this case, radiant heat will at least partly, if not chiefly, consist, if I may be permitted the expression, of invisible light; that is to say, of rays coming from the sun, that have such a momentum as to be unfit for vision. And admitting, as is highly probable, that the organs of sight are only adapted to receive impressions from particles of a certain momentum, it explains why the maximum of illumination should be in the middle of the refrangible rays; as those which have greater or less momenta are likely to become equally unfit for the impression of sight.”

William Herschel (1738–1822) German-born British astronomer, technical expert, and composer

Source: Sir William Herschel: His Life and Works (1880), Ch.4 "Life and Works" on his discovery of the infrared light.

William Herschel photo

“This consideration must alter the form of our proposed inquiry; for the question being thus at least partly decided, since it is ascertained that we have rays of heat which give no light, it can only become a subject of inquiry whether some of these heat-making rays may not have a power of rendering objects visible, superadded to their now already established power of heating bodies.”

William Herschel (1738–1822) German-born British astronomer, technical expert, and composer

This being the case, it is evident that the onus probandi [burden of proof] ought to lie with those who are willing to establish such an hypothesis, for it does not appear that Nature is in the habit of using one and the same mechanism with any two of our senses. Witness the vibration of air that makes sound, the effluvia that occasion smells, the particles that produce taste, the resistance or repulsive powers that affect the touch—all these are evidently suited to their respective organs of sense.
Source: Sir William Herschel: His Life and Works (1880), Ch.4 "Life and Works" on his discovery of the infrared.

George Berkeley photo

“Since therefore, as well those degrees of heat that are not painful, as those that are, can exist in a thinking substance; may we not conclude that external bodies are absolutely incapable of any degree of heat whatsoever?”

George Berkeley book Three Dialogues between Hylas and Philonous

Philonous to Hylas. Hylas replies with, "So it seems".
Three Dialogues between Hylas and Philonous (1713)

Rudolf Clausius photo

“My memoirs "On the Mechanical Theory of Heat" are of different kinds. Some are devoted to the development of the general theory and to the application thereof to those properties of bodies which are usually treated of in the doctrine of heat. Others have reference to the application of the mechanical theory of heat to electricity. …Other memoirs… have reference to the conceptions I have formed of the molecular motions which we call heat. These conceptions, however, have no necessary connexion with the general theory, the latter being based solely on certain principles which may be accepted without adopting any particular view as to the nature of molecular motions. I have therefore kept the consideration of molecular motions quite distinct from the exposition of the general theory.”

Rudolf Clausius (1822–1888) German mathematical physicist

Preface (August, 1864)
The Mechanical Theory of Heat (1867)

William Herschel photo

“This consideration must alter the form of our proposed inquiry; for the question being thus at least partly decided, since it is ascertained that we have rays of heat which give no light, it can only become a subject of inquiry whether some of these heat-making rays may not have a power of rendering objects visible, superadded to their now already established power of heating bodies. This being the case, it is evident that the onus probandi [burden of proof] ought to lie with those who are willing to establish such an hypothesis, for it does not appear that Nature is in the habit of using one and the same mechanism with any two of our senses. Witness the vibration of air that makes sound, the effluvia that occasion smells, the particles that produce taste, the resistance or repulsive powers that affect the touch—all these are evidently suited to their respective organs of sense.”

William Herschel (1738–1822) German-born British astronomer, technical expert, and composer

Source: Sir William Herschel: His Life and Works (1880), Ch.4 "Life and Works" on his discovery of the infrared.

Rudolf Clausius photo

“Many facts have lately transpired which tend to overthrow the hypothesis that heat is itself a body, and to prove that it consists in a motion of the ultimate particles of bodies. If this be so, the general principles of mechanics may be applied to heat; this motion may be converted into work, the loss of vis viva in each particular case being proportional to the quantity of work produced.
These circumstances, of which Carnot was also well aware, and the importance of which he expressly admitted, pressingly demand a comparison between heat and work, to be undertaken with reference to the divergent assumption that the production of work is not only due to an alteration in the distribution of heat, but to an actual consumption thereof; and inversely, that by the expenditure of work, heat may be produced.”

Rudolf Clausius (1822–1888) German mathematical physicist

First Memoir.
The Mechanical Theory of Heat (1867)

Nicolas Léonard Sadi Carnot photo

“[W]hen a body has experienced any changes, and when after a certain number of transformations it returns to precisely its original state, that is, to that state considered in respect to density, to temperature, to mode of aggregation—let us suppose, I say, that this body is found to contain the same quantity of heat that it contained at first, or else that the quantities of heat absorbed or set free in these different transformations are exactly compensated. This fact has never been called in question. It was first admitted without reflection, and verified afterwards in many cases by experiments with the calorimeter. To deny it would be to overthrow the whole theory of heat to which it serves as a basis. For the rest, we may say in passing, the main principles on which the theory of heat rests require the most careful examination. Many experimental facts appear almost inexplicable in the present state of this theory.”

Nicolas Léonard Sadi Carnot (1796–1832) French physicist, the "father of thermodynamics" (1796–1832)

Reflections on the Motive Power of Heat (1824)

Joseph Fourier photo

“Primary causes are unknown to us; but are subject to simple and constant laws, which may be discovered by observation, the study of them being the object of natural philosophy.
Heat, like gravity, penetrates every substance of the universe, its rays occupy all parts of space. The object of our work is to set forth the mathematical laws which this element obeys. The theory of heat will hereafter form one of the most important branches of general physics.”

Joseph Fourier book The Analytical Theory of Heat

Source: The Analytical Theory of Heat (1878), Ch. 1, p. 1

William Thomson photo

“The beauty and clearness of the dynamical theory, which asserts heat and light to be modes of motion, is at present obscured by two clouds.”

William Thomson (1824–1907) British physicist and engineer

From a 1900, April 27, , Sixth Series, 2, 1–40 (1901).
Thermodynamics quotes
Context: The beauty and clearness of the dynamical theory, which asserts heat and light to be modes of motion, is at present obscured by two clouds. I. The first came into existence with the undulatory theory of light, and was dealt with by Fresnel and Dr. Thomas Young; it involved the question, how could the earth move through an elastic solid, such as essentially is the luminiferous ether? II. The second is the Maxwell–Boltzmann doctrine regarding the partition of energy.

Nicolas Léonard Sadi Carnot photo

“Heat can evidently be a cause of motion only by virtue of the changes of volume or of form which it produces in bodies.”

Nicolas Léonard Sadi Carnot (1796–1832) French physicist, the "father of thermodynamics" (1796–1832)

p, 125
Reflections on the Motive Power of Heat (1824)

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