“I have endeavoured to attain this end (viz. the production of a vacuum in the cylinder) in another way. As water has the property of elasticity, when converted into steam by heat, and afterwards of being so completely recondensed by cold, that there does not remain the least appearance of this elasticity, I have thought that it would not be difficult to work machines in which, by means of a moderate heat and at a small cost, water might produce that perfect vacuum which has vainly been sought by means of gunpowder.”

— Denis Papin

Denis Papin, Recueil de diverses Pièces touchant quelques nouvelles Machines (1695) p. 53 as quoted by Dionysius Lardner, The Steam Engine Explained and Illustrated (1840) pp. 45-46

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Denis Papin 7

French physicist, mathematician and inventor 1647–1713

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“By another way, therefore, I endeavoured to attain the same end; and since it is a property of water that a small quantity of it, converted into steam by the force of heat, has an elastic force like that of the air, but, when cold supervenes, is again resolved into water, so that no trace of the said elastic force remains; I felt confident that machines might be constructed wherein water, by means of no very intense heat, and at small cost, might produce that perfect vacuum which had failed to be obtained by aid of gunpowder. But of the various constructions which can be contrived for this purpose, the following seemed to me to be the most suitable.”

Denis Papin (1647–1713) French physicist, mathematician and inventor

"A New Method of Obtaining Very Great Moving Powers at Small Cost" (1690)

“What happens… in a steam-engine…? The caloric developed in the furnace by the effect of the combustion traverses the walls of the boiler, produces steam, and in some way incorporates itself with it. The latter carrying it away, takes it first into the cylinder, where it performs some function, and from thence into the condenser, where it is liquefied by contact with the cold water… [T]he cold water of the condenser takes possession of the caloric… It is heated by the intervention of the steam as if it had been placed directly over the furnace. The steam is here only a means of transporting the caloric.”

Nicolas Léonard Sadi Carnot (1796–1832) French physicist, the "father of thermodynamics" (1796–1832)

p, 125
Reflections on the Motive Power of Heat (1824)

“The steam-engine having furnished us with a means of converting heat into a motive power, and our thoughts being thereby led to regard a certain quantity of work as an equivalent for the amount of heat expended in its production, the idea of establishing theoretically some fixed relation between a quantity of heat and the quantity of work which it can possibly produce, from which relation conclusions regarding the nature of heat itself might be deduced, naturally presents itself. Already, indeed, have many successful efforts been made with this view; I believe, however, that they have not exhausted the subject, but that, on the contrary, it merits the continued attention of physicists… The most important investigation in connexion with this subject is that of S. Carnot.”

Rudolf Clausius (1822–1888) German mathematical physicist

First Memoir. On the Moving Force of Heat and the Laws which may be Deduced Therefrom
The Mechanical Theory of Heat (1867)

“I have… attempted to throw some new light on the general properties of matter in other forms: and on the doctrine of heat, which is materially concerned in them; and to deduce some useful conclusions from a comparison of various experiments on the elasticity of steam, on evaporation, and on the indications of hygrometers.”

Thomas Young (scientist) (1773–1829) English polymath

Preface
A Course of Lectures on Natural Philosophy and the Mechanical Arts (1807)

“The phenomenon of the production of motion by heat has not been considered from a sufficiently general point of view. We have considered it only in machines… [for which] the phenomenon is… incomplete. It becomes difficult to recognize its principles and study its laws. …[T]he principle of the production of motion by heat… must be considered independently of any mechanism or… particular agent. It is necessary to establish principles applicable not only to steam-engines but to all imaginable heat-engines, whatever the working substance and whatever the method by which it is operated.”

Nicolas Léonard Sadi Carnot (1796–1832) French physicist, the "father of thermodynamics" (1796–1832)

Reflections on the Motive Power of Heat (1824)

“Is not the Heat of the warm Room convey'd through the Vacuum by the Vibrations of a much subtiler Medium than Air, which after the Air was drawn out remained in the Vacuum?”

Isaac Newton book Opticks, or a Treatise of the Reflections, Refractions, Inflections and Colours of Light

And is not this Medium the same with that Medium by which Light is refracted and reflected and by whose Vibrations Light communicates Heat to Bodies, and is put into Fits of easy Reflexion and easy Transmission? ...And do not hot Bodies communicate their Heat to contiguous cold ones, by the Vibrations of this Medium propagated from them into the cold ones? And is not this Medium exceedingly more rare and subtile than the Air, and exceedingly more elastick and active? And doth it not readily pervade all Bodies? And is it not (by its elastick force) expanded through all the Heavens?
Query 18
Opticks (1704)

“I perceived that, in order to make the best use of steam, it was necessary—first, that the cylinder should be maintained always as hot as the steam which entered it; and, secondly, that when the steam was condensed, the water of which it was composed, and the injection itself, should be cooled down to 100°, or lower, where that was possible. The means of accomplishing these points did not immediately present themselves; but early in 1765 it occurred to me, that if a communication were opened between a cylinder containing steam, and another vessel which was exhausted of air and other fluids, the steam, as an elastic fluid, would immediately rush into the empty vessel, and continue so to do until it had established an equilibrium; and if that vessel were kept very cool by an injection, or otherwise, more steam would continue to enter until the whole was condensed.”

James Watt (1736–1819) British engineer

"Notes on Professor Robison's Dissertation on Steam-engines" (1769)

“Other qualities of bodies are connected with simple energy of motion and energy of position. Such is heat, which we find by experiment can be turned into work. Finding it convertible with energy, we call it a form of energy. ...But as to heat, it is further established by experiment that in this case the energy of motion does really persist as such. Thus a gas consists of molecules flying about with velocity, rotating and vibrating, and so having energy motion. All this energy of motion is what we call heat, and thus heat is a repetition of a known meaning of energy. Again, heat exists between a radiating body and the thing it warms; now the intermediate space is filled by the luminiferous ether, which, being elastic, has in its ultimate parts both energy of motion energy of position. In these forms the heat exists in the space in question.”

William Kingdon Clifford (1845–1879) English mathematician and philosopher

"Energy and Force" (Mar 28, 1873)

“One of the steam vessels being filled with steam, condensation was produced by projecting cold water”

Thomas Tredgold (1788–1829) engineer

The Steam Engine: Comprising an Account of Its Invention and Progressive Improvement, 1827
Context: In June, 1699, Captain Savery exhibited a model of his engine before the Royal Society, and the experiments he made with it succeeded to their satisfaction. It consisted of a furnace and boiler B: from the latter, two pipes, provided with cocks C, proceeded to two steam vessels S, which had branch pipes from a descending main D, and also to a rising main pipe A: each pair of branch pipes had [check] valves a, b to prevent the descent of the water raised by the condensation or by the force of steam. Only one vessel, S, is shown, the other being immediately behind it. One of the steam vessels being filled with steam, condensation was produced by projecting cold water, from a small cistern E, against the vessel; and into the partial vacuum made by that means, the water, by the pressure of the atmosphere, was forced up the descending main D, from a depth of about twenty feet; and on the steam being let into the vessels again, the valve b closed, and prevented the descent of the water, while the steam having acquired force in the boiler, its pressure caused the water to raise the valve a, and ascend to a height proportional to the excess of the elastic force of the steam above the pressure of the air.

“Many facts have lately transpired which tend to overthrow the hypothesis that heat is itself a body, and to prove that it consists in a motion of the ultimate particles of bodies. If this be so, the general principles of mechanics may be applied to heat; this motion may be converted into work, the loss of vis viva in each particular case being proportional to the quantity of work produced.
These circumstances, of which Carnot was also well aware, and the importance of which he expressly admitted, pressingly demand a comparison between heat and work, to be undertaken with reference to the divergent assumption that the production of work is not only due to an alteration in the distribution of heat, but to an actual consumption thereof; and inversely, that by the expenditure of work, heat may be produced.”

Rudolf Clausius (1822–1888) German mathematical physicist

First Memoir.
The Mechanical Theory of Heat (1867)

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